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No. of Recommendations: 1
Do not put chemicals in the toilet tank. I don't know exactly which chemical some cleaning people started putting in our toilet tanks about 10 years ago - but I observed a few months into that experience that the brass screws that held the tank on the toilet bowl were being chemically dissolved.

Pumice is not going to harm porcelain in my opinion. Other options include Bar Keepers Friend and Comet brand cleaner.
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